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Elements of Chemical Reaction Engineering
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Elements of Chemical Reaction Engineering Hardcover - 2005

by H. Scott Fogler


Summary

The fundamentals of chemical reaction engineering is a verbose resource in its field.The book presents in a clear and concise manner the fundamentals of chemical reaction engineering. The structure of the book allows the student to solve reaction engineering problems through reasoning rather than through memorization and recall of numerous equations, restrictions, and conditions under which each equation applies. The fourth edition contains more industrial chemistry with real reactors and real engineering and extends the wide range of applications to which chemical reaction engineering principles can be applied (i.e., cobra bites, medications, ecological engineering)

From the publisher

This book combines authoritative coverage of the principles of chemical reaction engineering with an unsurpassed focus on critical thinking and creative problem solving. Clear, concise, and superbly organized, it integrates text, visuals, and computer simulations to help readers solve even the most challenging problems through reasoning, rather than by memorizing equations.

First line

HASH(0x17e2dc50)

Details

  • Title Elements of Chemical Reaction Engineering
  • Author H. Scott Fogler
  • Binding Hardcover
  • Edition 4th ed.
  • Pages 1120
  • Volumes 1
  • Language ENG
  • Publisher Prentice Hall, Lebanon, Indiana, U.s.a.
  • Date August 23, 2005
  • ISBN 9780130473943 / 0130473944
  • Weight 3.6 lbs (1.63 kg)
  • Dimensions 9.4 x 7.2 x 1.7 in (23.88 x 18.29 x 4.32 cm)
  • Library of Congress subjects Chemical reactors
  • Library of Congress Catalog Number 2004060140
  • Dewey Decimal Code 660.283

Table of contents

1. Mole Balances. The Rate of Reaction The General Mole Balance Equation Batch Reactors Continuous-Flow Reactors Industrial Reactors Summary CD-ROM Material Questions and Problems Supplementary Reading2. Conversion and Reactor Sizing. Definition of Conversion Batch Reactor Design Equations Design Equations for Flow Reactors Applications of the Design Equations for Continuous-Flow Reactors Reactors in Series Some Further Definitions Summary CD-ROM Materials Questions and Problems Supplementary Reading3. Rate Laws and Stoichiometry. Part 1. Rate Laws Basic Definitions The Reaction Order and the Rate Law The Reaction Rate Constant Present Status of Our Approach to Reactor Sizing and Design Part 2. Stoichiometry Batch Systems Flow Systems Summary CD-ROM Material Questions and Problems Supplementary Reading4. Isothermal Reactor Design. Part 1. Mole Balances in Terms of Conversion Design Structure for Isothermal Reactors Scale-Up of Liquid-Phase Batch Reactor Data to the Design of a CSTR Design of Continuous Stirred Tank Reactors (CSTRs) Tubular Reactors Pressure Drop in Reactors Synthesizing the Design of a Chemical Plant Part 2. Mole Balances Written in Terms of Concentration and Molar Flow Rate Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors Microreactors Membrane Reactors Unsteady-State Operation of Stirred Reactors The Practical Side Summary ODE Solver Algorithm CD-ROM Material Questions and Problems Some Thoughts on Critiquing What You read Journal Critique Problems Supplementary Reading5. Collection and Analysis of Rate Data. The Algorithm for Data Analysis Batch Reactor Data Method of Initial Rates Method of Half-Lives Differential Reactors Experimental Planning Evaluation of Laboratory Reactors Summary CD-ROM Material Questions and Problems Journal Critique Problems Supplementary Reading6. Multiple Reactions. Definitions Parallel Reactions Maximizing the Desired Product in Series Reactions Algorithm for Solution of Complex Reactions Multiple Reactions in a PFR/PBR Multiple Reactions in a CSTR Membrane Reactors to Improve Selectivity in Multiple Reactions Complex Reactions of Ammonia Oxidation Sorting It All Out The Fun Part Summary CD-ROM Material Questions and Problems Journal Critique Problems Supplementary Reading7. Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors. Active Intermediates and Nonelementary Rate Laws Enzymatic Reaction Fundamentals Inhibition of Enzyme Reactions Bioreactors Physiologically Based Pharmacokinetic (PBPK) Models Summary CD-ROM Material Questions and Problems Journal Critique Problems Supplementary Reading8. Steady-State Nonisothermal Reactor Design. Rationale The Energy Balance Adiabatic Operation Steady-State Tubular Reactor with Heat Exchange Equilibrium Conversion CSTR with Heat Effects Multiple Steady States Nonisothermal Multiple Chemical Reactions Radial and Axial Variations in a Tubular Reactor The Practical Side Summary CD-ROM Material Questions and Problems Journal Critique Problems Supplementary Reading9. Unsteady-State Nonisothermal Reactor Design. The Unsteady-State Energy Balance Energy Balance on Batch Reactors Semibatch Reactors with a Heat Exchanger Unsteady Operation of a CSTR Nonisothermal Multiple Reactions Unsteady Operation of Plug-Flow Reactors Summary CD-ROM Material Questions and Problems Supplementary Reading10. Catalysis and Catalytic Reactors. Catalysts Steps in a Catalytic Reaction Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step Heterogeneous Data Analysis for Reactor Design Reaction Engineering in Microelectronic Fabrication Model Discrimination Catalyst Deactivation Summary ODE Solver Algorithm CD-ROM Material Questions and Problems Journal Critique Problems Supplementary Reading11. External Diffusion Effects on Heterogeneous Reactions. Diffusion Fundamentals Binary Diffusion External Resistance to Mass Transfer What If . . . ? (Parameter Sensitivity) The Shrinking Core Model Summary CD-ROM Material Questions and Problems Supplementary Reading12. Diffusion and Reaction. Diffusion and Reaction in Spherical Catalyst Pellets Internal Effectiveness Factor Falsified Kinetics Overall Effectiveness Factor Estimation of Diffusion- and Reaction-Limited Regimes Mass Transfer and Reaction in a Packed Bed Determination of Limiting Situations from Reaction Data Multiphase Reactors Fluidized Bed Reactors Chemical Vapor Deposition (CVD) Summary CD-ROM Material Questions and Problems Journal Article Problems Journal Critique Problems Supplementary Reading13. Distributions of Residence Times for Chemical Reactors. General Characteristics Part 1. Characteristics and Diagnostics Measurement of the RTD Characteristics of the RTD RTD in Ideal Reactors Diagnostics and Troubleshooting Part 2. Predicting Conversion and Exit Concentration Reactor Modeling Using the RTD Zero-Parameter Models Using Software Packages RTD and Multiple Reactions Summary CD-ROM Material Questions and Problems Supplementary Reading14. Models for Nonideal Reactors. Some Guidelines Tanks-in-Series (T-I-S) Model Dispersion Model Flow, Reaction, and Dispersion Tanks-in-Series Model Versus Dispersion Model Numerical Solutions to Flows with Dispersion and Reaction Two-Parameter Models-Modeling Real Reactors with Combinations of Ideal Reactors Use of Software Packages to Determine the Model Parameters Other Models of Nonideal Reactors Using CSTRs and PFRs Applications to Pharmacokinetic Modeling Summary CD-ROM Material Questions and Problems Supplementary ReadingAppendix A: Numerical Techniques.Appendix B: Ideal Gas Constant and Conversion Factors.Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant.Appendix D: Measurement of Slopes on Semilog Paper.Appendix E: Software Packages.Appendix F: Nomenclature.Appendix G: Rate Law Data.Appendix H: Open-Ended Problems.Appendix I: How to Use the CD-ROM.Appendix J: Use of Computational Chemistry Software Packages.Index.About the CD-ROM.

About the author

H. Scott Fogler is the Arthur F. Thurnau Professor, Vennema Professor of Chemical Engineering at the University of Michigan. His research interests include flow and reaction in porous media, fused chemical relations, gellation kinetics, and chemical reaction engineering problems in the petroleum industry. He has graduated 37 Ph.D. students and has more than 200 refereed publications in these areas. Fogler is the AIChE 2008 President-elect. He has chaired ASEE's Chemical Engineering Division, served as director of the American Institute of Chemical Engineers, earned the Warren K. Lewis Award from AIChE for contributions to chemical engineering education, and received the Chemical Manufacturers Association's National Catalyst Award. He is the co-author of the bestselling textbook Strategies for Creative Problem Solving, Second Edition (Prentice Hall, 2008).
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